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Wednesday, March 21, Quantum plasmons demonstrated in atomic-scale nanoparticles ScienceDaily Mar. Addressing a half-decade-old debate, engineers at Stanford have positively identified the presence of plasmons, the collective oscillations of electrons, in individual metal particles as Sony Vaio VPCEG32FX Image Optimizer as one nanometer in diameter. The discovery could impact nanotechnology.
The physical phenomenon of plasmon resonances in small metal particles has been apparent for centuries. They are visible in the vibrant hues of the great stained-glass windows of the world. More recently, plasmon resonances have been used by engineers to develop new, Sony Vaio VPCEG32FX Image Optimizer cancer treatments and to enhance light absorption in photovoltaics and photocatalysis.
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When the windows are illuminated, the nanoparticles scatter specific colors depending on the particle's size and geometry " said Jennifer Dionne, an assistant professor of materials science and engineering at Stanford and the senior author of a new paper on plasmon resonances to be published in the journal Nature. In the Sony Vaio VPCEG32FX Image Optimizer, the team of engineers report the direct observation of plasmon resonances in individual metal particles measuring down to one nanometer in diameter, just a few atoms across. Exploring their size-dependent nature could open up some interesting applications at the nanoscale. Longstanding debate The Sony Vaio VPCEG32FX Image Optimizer of tiny metal particles has perplexed physicists and engineers for decades.
As metallic particles near about 10 nanometers in diameter, classical physics breaks down. The particles begin to demonstrate unique physical and chemical properties that bulk counterparts of the very same materials do not. A nanoparticle of silver measuring a few atoms across, for instance, will respond to photons and electrons in ways profoundly different from a larger particle or slab of silver.
Sony Vaio VPCEG32FX Image Optimizer clearly illustrating the details of this classical-to-quantum transition, Scholl and Dionne have pushed the field of plasmonics into a new realm that could have lasting consequences for catalytic processes such as artificial photosynthesis, for cancer research and treatment, and even quantum computing. This paper provides the foundation for new avenues of nanotechnology entering the to, atom regime.
These metals are well known to support localized surface plasmon resonances in larger particles. Plasmons are Sony Vaio VPCEG32FX Image Optimizer collective oscillation of electrons at the metal surface in response to light or an electric field. Additionally, other important physical properties can be driven when plasmons are constrained in extremely small spaces, like the nanoparticles Dionne and Scholl studied, a phenomenon known as quantum confinement.
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Depending on the shape and size of the particle, therefore, quantum confinement can dominate a particle's electronic and optical response. This research allows scientists, for the first time, to directly correlate a quantum-sized plasmonic particle's geometry -- its shape and size -- with its plasmon resonances. Standing to benefit Nanotechnology stands to benefit from this new understanding. Medical science, for instance, has devised a way to use nanoparticles excited by light Sony Vaio VPCEG32FX Image Optimizer burn away cancer cells, a process known as photothermal ablation.
Metal nanoparticles are affixed with molecular appendages called ligands that attach exclusively to chemical receptors on cancerous cells. When irradiated with infrared light, the plasmons begin to resonate and the metal nanoparticles heat up, burning away the cancerous cells while leaving the surrounding healthy tissue unaffected.
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The use of smaller nanoparticles in these therapies might improve their accuracy and the effectiveness, particularly since they can be more easily integrated into cells. There is great promise for such small nanoparticles in catalysis, as well.
The greater surface-area-to-volume ratios Sony Vaio VPCEG32FX Image Optimizer by atomic-scale nanoparticles could could significantly improve catalyic rates and efficiencies and provide advances in water-splitting and artificial photosynthesis, yielding clean and renewable energy sources from artificial fuels. Aiding and abetting The researchers' ability to observe plasmons in particles of Sony Vaio VPCEG32FX Image Optimizer small size was abetted by the powerful, multi-million dollar environmental scanning transmission electron microscope E-STEM installed recently at Stanford's Center for Nanoscale Science and Engineering, one of just a handful of such microscopes in the world. E-STEM imaging was used in conjunction with electron energy-loss spectroscopy EELS -- a research technique that measures the change in an electron's energy as it passes through a material -- to determine the shape and behavior of individual nanoparticles.
We have clarified what was an ambiguous scientific understanding and, for the first time, directly correlated a particle's geometry Sony Vaio VPCEG32FX Image Optimizer its plasmonic resonance for quantum-sized particles," summarized Dionne. Other social bookmarking and sharing tools: The above story is reprinted from materials provided by Stanford School of Engineering.
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The original article was written by Andrew Myers. Materials may be edited for content and length.
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For further information, please contact the source cited above. Quantum plasmon resonances of individual metallic nanoparticles. Nature, ; Benefits and improvements. This utility installs an updated version of the VAIO® Image Optimizer software to resolve an issue where MP4 video files recorded. Unless stated otherwise, the file listed below must be installed BEFORE the VAIO Image Optimizer Sony Vaio VPCEG32FX Image Optimizer (Windows 64bit, Windows 8 64bit) in order for it to.